Nanjing K.K. Chemical provides professional water treatment solutions!
Nanjing Kaiguang Chemical provides professional water treatment solutions!

Molybdenum Removal Wastewater Test


Key Points of Recent Amendments and Additions to the Effluent Discharge Standards (4/8)

The Environmental Protection Administration of the Executive Yuan amended and announced on December 25, 2017, that starting from 2021 (next year), some control items of the effluent discharge standards will be tightened and new ones will be added. Based on improving water body quality and reducing the risk of agricultural land pollution, control items and limits such as ammonia nitrogen, heavy metals, carcinogenic substances, and true color chroma have been amended.

Key Points of Recent Amendments and Additions to the Effluent Discharge Standards (4/8)

Key Points of Recent Amendments and Additions to the Effluent Discharge Standards - Tightening and Newly Added Heavy Metals

Implemented in stages - Tighten the control limits of 9 heavy metals including cadmium, lead, total chromium, hexavalent chromium, copper, zinc, nickel, selenium, and arsenic, and add control items such as tin and molybdenum.

Key Points of Recent Amendments and Additions to the Effluent Discharge Standards - Tightening of Heavy Metals
Key Points of Recent Amendments and Additions to the Effluent Discharge Standards - Newly Added Heavy Metals

In order to further improve the overall water quality in Taiwan, reduce the amount of pollution borne by water bodies, and improve river water quality. The Environmental Protection Administration of the Executive Yuan tightened regulations and added regulations for some specific industries in 2024 and 2027. Detailed control items can be viewed on the website of the Environmental Protection Administration of the Executive Yuan.

Experiment on Molybdenum Removal from RM Wastewater in a Steel Plant

I. Problem Discussion

According to a steel plant in the south, there is a problem that the molybdenum content in the RM wastewater effluent from the plant exceeds the discharge standard.

On May 12, 2021, we went to understand the reasons and abnormal issues and took samples for molybdenum content analysis: 21 - 23 ppm. (The effluent discharge standard is 0.6 ppm), and the allowable discharge content gap is 35 times.

Given that molybdenum pollution in the plant is a frequent situation and is caused by the manufacturing process. We closely cooperated with the plant staff to discuss treatment methods.

Therefore, Kaiguang proposed: Physical Equipment Treatment Method

Physical Equipment Treatment Method:
Introduce the imported as the main treatment procedure, and design a treatment process with one in use and one in standby to ensure that the molybdenum content meets the effluent discharge standard of less than 0.6 ppm. Through the physical equipment treatment process, the is used for treatment to meet the discharge standard. When it is saturated, the catalyst's effectiveness can be restored through a backwashing procedure, and repeated treatment can meet the discharge standard.

Therefore, on May 17, Kaiguang cooperated with a steel plant in the south to conduct experimental tests on using a large amount of RM wastewater from the plant.

In response to the increasingly tightened discharge standards, Kaiguang is also actively cooperating with many partner manufacturers. Regarding the problems that trouble customers, we assist in conducting relevant experiments and tests, and help customers plan wastewater treatment processes to meet regulatory standards in the future.

Inspection Time First Analysis on May 17 Second Analysis on May 17
Adjusted Retention Time
Molybdenum Content 2 ppm 0.4 ppm
 
II. Experimental Test of Molybdenum Metal Adsorption Catalyst

On May 17, 2021, the first test was conducted. The molybdenum content analysis of the raw water: 21 PPM

This test confirmed that this method can effectively remove molybdenum. However, due to the relatively dirty quality of the wastewater, containing oil and suspended solids, it is easy to cause catalyst blockage.

On May 18, 2021, a second test was conducted. The raw wastewater was filtered to remove oil and suspended solids, and the molybdenum content was continuously monitored. The molybdenum content of the raw water: 21 ppm, 23 ppm
From May 20 to May 24, a third test was conducted. The catalyst was backwashed, and the retention time was adjusted for continuous treatment and intermittent monitoring. The molybdenum content of the raw water: 21 ppm

May 18 May 20 May 21 May 24
Inspection Time / Molybdenum Content
08:40 / 1.7 ppm 09:40 / 1.1 ppm 11:40 / 0.8 ppm 09:30 / 0.5 ppm 09:30 / 0.5 ppm 09:30 / 0.6 ppm
13:30 / 1.5 ppm 14:30 / 0.9 ppm 15:40 / 0.8 ppm 13:30 / 0.3 ppm 13:30 / 0.7 ppm 13:30 / 0.5 ppm
16:40 / 0.4 ppm 17:40 / 0.8 ppm - 17:30 / 0.4 ppm 17:30 / 0.4 ppm 17:30 / 0.5 ppm
Experimental Test of Molybdenum Metal Adsorption Catalyst 01
Experimental Test of Molybdenum Metal Adsorption Catalyst 02
Experimental Test of Molybdenum Metal Adsorption Catalyst 03

After the experimental test of the molybdenum metal adsorption catalyst, it has been determined that this is an executable physical treatment method. It can effectively remove molybdenum content to meet the discharge standard.